Measurement of 15 N longitudinal relaxation rates in 15 NH 4 + spin systems to characterise rotational correlation times and chemical exchange
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چکیده
منابع مشابه
Heteronuclear NMR spectroscopy for lysine NH(3) groups in proteins: unique effect of water exchange on (15)N transverse relaxation.
In this paper, we present a series of heteronuclear NMR experiments for the direct observation and characterization of lysine NH3 groups in proteins. In the context of the HoxD9 homeodomain bound specifically to DNA we were able to directly observe three cross-peaks, arising from lysine NH3 groups, with 15N chemical shifts around approximately 33 ppm at pH 5.8 and 35 degrees C. Measurement of w...
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We compared gross N fluxes by N pool dilution in a coarse-textured agricultural soil when N was applied to the soil NH4 C pool by either: (i) mixing a NH4NO3 solution into disturbed soil or (ii) injection of NH3 gas into intact soil cores. The two techniques produced similar results for gross N mineralization rates indicating that NH4 C production in soil was not altered by soil disturbance, me...
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Single spins in solid-state systems are often considered prime candidates for the storage of quantum information, and their interaction with the environment the main limiting factor for the realization of such schemes. The lifetime of an excited spin state is a sensitive measure of this interaction, but extending the spatial resolution of spin relaxation measurements to the atomic scale has bee...
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Department of Earth, Environmental and Planetary Sciences, Rice University, Houston, TX 77005, USA. Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, Los Angeles, CA 90089, USA. Department of Integrative Biology and Department of Energy Great Lakes Bioenergy Research Center, Michigan State University, East Lansing, MI 48824, USA. Department of Earth and ...
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ژورنال
عنوان ژورنال: Journal of Magnetic Resonance
سال: 2017
ISSN: 1090-7807
DOI: 10.1016/j.jmr.2017.01.015